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Conductive Phthalocyanine-Based Metal-Organic Frameworks for Efficient Electrocatalysis
Lu, Shun; Liu, Yuan; Liu, Hong
2024-03-24
摘要The development of innovative catalysts for various electrochemical scenarios is crucial in satisfying the growing demands for sustainable energy and environmental conservation. Conductive metal -organic frameworks (c-MOFs) based on phthalocyanine complexes known as phthalocyanine-based c-MOFs, have shown promising potential in electrochemical energy conversion and environmental research. These c-MOFs represent a new category of layer -stacked porous MOFs with in -plane extended pi-conjugation structure, which can enhance electrocatalytic activity by facilitating the mass diffusion of reactants and electron/charge transfer. The exceptional promising for a variety electrocatalytic reactions, such as water, oxygen, CO 2 , and nitrogen conversion. In this work, we focus primarily on phthalocyanine-based c-MOFs rather than other types of c-MOFs, providing a comprehensive overview of their conductive mechanisms and main electrocatalytic reactions. We also cover recent progress in the utilization of phthalocyanine-based c-MOFs as heterogeneous catalysts in electrocatalysis. Furthermore, we explore the challenges related to the utilization of phthalocyanine-based c-MOFs in electrocatalysis. The state-of-the-art research and insights into the future perspectives of phthalocyanine-based c-MOFs as electrocatalysts are also presented and discussed. This work aim to guide the development of phthalocyanine-based c-MOF electrocatalysts with enhanced activity.
关键词Key words conductive metal-organic frameworks phthalocyanine-based MOFs conjugated structure electrocatalysis
DOI10.7536/PC231115
发表期刊PROGRESS IN CHEMISTRY
ISSN1005-281X
卷号36期号:3页码:285-296
通讯作者Liu, Hong(liuhong@cigit.ac.cn)
收录类别SCI
WOS记录号WOS:001221735100003
语种英语