KMS Chongqing Institute of Green and Intelligent Technology, CAS
| Analysis of the Thermal Aging Kinetics of Tallow, Chicken Oil, Lard, and Sheep Oil | |
Hsieh, Yun-Chuan1; Ouyang, Hao1; Zhang, Yulin2; Chiang, Donyau3; Yang, Fuqian4; Chen, Hsin-Lung5; Lee, Sanboh1
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| 2024-09-01 | |
| 摘要 | Understanding the thermal aging kinetics of animal oils is of vital importance in the storage and applications of animal oils. In this work, we use four different techniques, including UV-Vis spectrometry, viscometry, impedance spectroscopy, and acid-base titration, to study the thermal aging kinetics of tallow, chicken oil, lard, and sheep oil in the temperature range from 120 degrees C to 180 degrees C. The evolutions of the UV-Vis absorbance, dynamic viscosity, electric impedance, and acid titration are discussed with the defect kinetics. The evolutions of the color centers, defects for dynamic viscosity, and electric dipoles follow second-order, first-order, and zero-order kinetics, respectively. The temperature dependence of rate constants for the evolutions of the UV-Vis absorbance, dynamic viscosity, electric impedance, and acid titration satisfies the Arrhenius equation with the same activation energy for individual animal oils. The activation energies are similar to 43.1, similar to 23.8, similar to 39.1, and similar to 37.5 kJ/mol for tallow, chicken oil, lard, and sheep oil, respectively. The thermal aging kinetics of the animal oils are attributed to the oxidation of triglycerides. |
| 关键词 | animal oils UV-Vis spectrometry electrical impedance viscosity acid titration |
| DOI | 10.3390/molecules29174191 |
| 发表期刊 | MOLECULES
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| 卷号 | 29期号:17页码:15 |
| 通讯作者 | Lee, Sanboh(sblee@mx.nthu.edu.tw) |
| 收录类别 | SCI |
| WOS记录号 | WOS:001311672600001 |
| 语种 | 英语 |
